I'm not a big fan of the "curly" quotes. WordPress does them automatically – but this can really mess you up if you're copying and pasting code from a post. So I've turned them off…
As seen on this thread on the WP support forum – I've commented out all the lines at the end of vars.php (found in your includes folder) that look like this:
add_filter('the_SOMETHING', 'wptexturize');